Product ID:C&H 14EX SPRAY DETERGENT
MSDS Date:05/11/1999
FSC:6850
NIIN:01-415-7686
MSDS Number: CJRDM

C AND H CHEMICAL INC

222 STARKEY ST
SAINT PAUL, MN 55107
US

Emergency Phone: 800-228-5635 EXT 005

Info Phone: 612-227-4343

Cage: 0ZAU9

C AND H ENTERPRISES INC

SAINT PAUL, MN 55107 US

Telephone: 651-227-2485

Cage: 0ZAU9

SODIUM METASILICATE

CAS: 6834-92-0

RTECS: VV9275000

DIETHYLENE GLYCOL MONOBUTYL ETHER

CAS: 112-34-5

RTECS: KJ9100000

TRIETHANOLAMIN

CAS: 102-71-6

RTECS: KL9275000

ACGIH TLV: 5 MG/M3

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES-SEVERE IRRITATION.
SKIN-IRRITATION POSSIBLE WITH PROLONGED CONTACT. INHALATION OF
DUST OF PRODUCT OR MIST OF SOLUTION-IRRITATION OF RESPIRATORY
TRACT. SWALLOWING-IRRITATION OF MOUTH,THROA T & STOMACH. CHRONIC:
NONE EXPECTED BEYOND ACUTE EFFECTS. CONTAINS LESS THAN 5% AMINES.
THERE COULD POSSIBLY BE LIVER OR KIDNEY EFFECTS, WITH EXTENSIVE
OVER EXPOSURE, BASED ON ANIMAL STUDIES OF AMIN ES. ADDITIONALLY,
SOME PEOPLE DEVELOP SKIN SNESITIZATION TO AMINES.
Explanation of Carcinogenicity:PRODUCT OR ITS INGREDIENTS HAVE NOT BEEN
IDENTIFIED AS A CARCINOGEN OR POSSIBLE CARCINOGEN BY NTP, IARC
MONOGRAPHS, OR OSHA.
Effects of Overexposure:EYES-BURNS POSSIBLE. SKIN-BURNS POSSIBLE WITH
PROLONGED CONTACT. SWALLOWING-BURNS OF MOUTH, THROAT & STOMACH.
STOMACH UPSET.
Medical Cond Aggravated by Exposure:DERMATITIS AND SIMILAR SKIN
DISORDERS.

First Aid:EYE-IMMEDIATELY FLUSH WITH WATER FOR 15 MINS HOLDING LIDS
APART. REMOVE CONTACT LENSES IF PRESENT & CONTINUE FLUSHING FOR 15
MINS. GET MEDICAL AID. SKIN-IMMEDIATELY FLUSH WITH WATER FOR 15
MINS. REMO VE CONTAMINATED CLOTHING. IF IRRITATION OR BURN DEVELOPS
& PERSISTS, GET MEDICAL ADVICE OR AID. INHALED-REMOVE TO FRESH AIR.
IMMEDIATELY CALL FOR MEDICAL ADVICE OR AID IF BREATHING DIFFICULTY
OR IRRI TATION IS SEVERE OR CONTINUES. INGESTION-RINSE MOUTH WITH
WATER. DRINK WATER, MILK OR OTHER FLUIDS TO DILUTE. DO NOT INDUCE
VOMITING UNLESS DIRECTED BY MEDICAL PERSON. CALL FOR MEDICAL
ADVICE.

Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:AS NEEDED FOR SURROUNDING FIRE.
Fire Fighting Procedures:FOR ANY CHEMICAL FIRE WEAR SELF-CONTAINED
BREATHING APPARATUS, AND PROTECTIVE CLOTHING TO PREVENT CONTACT.
Unusual Fire/Explosion Hazard:NONE.

Spill Release Procedures:SMALL SPILLS, LESS THAN 2 POUNDS: RECOVER AS
PRACTICAL. FLUSH SPILL AREA TO DRAIN WITH EXCESS WATER. "SEE OTHER
INFORMATION"

Handling and Storage Precautions:HANDLING: AVOID UNNECESSARY CONTACT
W/PRODUCT. AVOID BREATH PRODUCT DUST/MISTS OF SOLUTION OF PRODUCT.
WASH IMMEDIATELY AFTER CONTACT. WASH AFTER USE. CLEANUP SPILLS
PROMPTLY TO PREVENT ACCIDENTAL CON TACT. PREVENT CONTACT WITH
INCOMPATIBLE MATERIALS.
Other Precautions:STORAG: KEEP CONTAINERS TIGHTLY CLOSED.KEEP PRODUCT
DRY TO PREVENT CAKING. **HAZARD IDENTIFICATION: HEALTH--2, FIRE--0,
INSTABILITY--0, OTHER--X. HAZARD SIGNAL (SHORT TERM CONTACT OR
INHALATION ONLY): HEALTH-2, FIRE-0, INSTABILITY-0, OTHER-X.
(0=INSIGNIFICANT; 1=SLIGHT; 2=MODERATE; 3=HIGH; 4=EXTREME ).

Respiratory Protection:NONE NORMALLY REQUIRED. WEAR NIOSH/MSHA APPROVED
RESPIRATOR WHERE CONDITIONS MAY CAUSE EXPOSURE LIMITS TO BE
EXCEEDED FROM DUST OF PRODUCT OR MISTS OF SOLUTIONS.
Ventilation:GENERAL OR LOCAL TO AVOID EXPOSURE TO DUST OR MISTS OF
SOLUTIONS.
Protective Gloves:CHEMICAL RESISTANT IMPERMEABLE GLOVES AS NEEDED TO
PREVENT EXCESSIVE CONTACT.
Eye Protection:GLASSES, GOGGLES, FACE SHIELD TO PREVENT EYE EXPOSURE
Other Protective Equipment:FULL BODY COVERING COVERING AND SHOES AS
NEEDED TO PREVENT EXCESSIVE COTNACT. EYE WASH STATION IN WORK AREA.
Work Hygienic Practices:WASH CONTAMINATED CLOTHING BEFORE REUSE. WASH
AFTER CONTACT. WASH AFTER USE.
Supplemental Safety and Health
PRODUCT DESCRIPTION: FREE FLOWING WHITE POWDER. CHEMICAL FAMILY:
ALKALINE DETERGENT. *PH:12+/-0.5 (2%SOLUTION).

HCC:B3
Boiling Pt:B.P. Text:N.E.
Vapor Pres:N.E.
Vapor Density:N.E.
Volatile Org Content %:1
Spec Gravity:N.E.
pH:12+/-0.5
Viscosity:NP
Evaporation Rate & Reference:NA
Solubility in Water:COMPLETE
Appearance and Odor:FREE FLOWING WHITE POWDER (ALKALINE DETERGENT)
Percent Volatiles by Volume:<2
Corrosion Rate:NP

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS.
Stability Condition to Avoid:CONTACT WITH INCOMPATIBLE MATERIALS.
Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN.
Conditions to Avoid Polymerization:HAZZARDOUS POLYMERIZATION WILL NOT
OCCUR.

Waste Disposal Methods:PRODUCT AND UN-NEUTRALIZED SOLUTIONS ARE
ALKALINE. NORMALLY SEWER DISPOSABLE IN DILUTE SOLUTIONS. CHECK WITH
LOCAL AUTHORITIES ABOUT ANY POSSIBLE RESTRICTIONS.

Toxicological Information:THRESHOLD LIMIT VALUE: N.E., BLEND PRODUCT.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO DATA.

Transport Information:DOT INFORMATION: 49 CFR 172.101. DOT DESCRIPTION:
NOT REGULATED BY D.O.T. CONTAINER/MODE: (POWDER) DRUM.

SARA Title III Information:SECTION 313 SUPPLIER NOTIFICATION:DIETHYLENE
GLYCOL BUTYL ETHER IS A CHEMICAL INGREDIENT SUBJECT TO REPORTING
REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY
RIGHT-TO-KNOWN ACT OF 1986. THIS INFORMATION SHOULD BE INCLUDED IN
ALL MSDS;S THAT ARE COPIED AND DISTRIBUTED FOR THIS MATERIAL.
CERCLA RQ-40 CFR 302.4 (A): NONE L;ISTED. SARA 302 COMPONENTS-40
CFR 355 APPENDIX A: NONE. S ECTION 311/312 HAZARD CLASS-40 CFR
370.2. SARA 313 COMPONENTS-40 CFR 372.65: DIETHYLENE GLYCOL BUTYL
ETHER CAS# 112-34-5--1.4%.
Federal Regulatory Information:US FEDERAL EGULATIONS: (TSCA TOXIC
SUBSTANCES CONTROL ACT) STATUS TSCA (UNITED STATES) THE INTENTIONAL
INGREDIENTS OF THIS PRODUCT ARE LISTED. INTERNATIONAL REGULATIONS
INVENTORY STATUS: NOT DETERMINE D.
State Regulatory Information:STATE AND LOCAL REGULATIONS: CALIFORNIA
PROPOSITION 65: NONE.